Indium Complexes of 1,3-Diphenyltriazene

DOI: 10.1039/DT9920002183

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2183 - 2192 (1992)

Update date:2022-08-05

Topics:

Authors:

Leman, John T.

Roman, Henry A.

Barron, Andrew R.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9920002183

The reaction of InCl3 with 1,3-diphenyltriazene (Hdpt) in the presence of NEt3 gives the six-co-ordinate indium complex 1a.The interaction of 1a with Cl and Cl allows for the isolation of the appropriate salts, 1b and 1c.Reaction of Lewis bases, L, with 1a yields , L = pyridine 2, 3,5-dimethylpyridine 3, PEt3 4, L2 = 2,2'-bipyridine 5, 1,10-phenanthroline 6, Me2PCH2CH2PMe2 7 or Et2PCH2CH2PEt2 8.The mechanism for these reactions is discussed.No rection is observed between 1b and 3,5-dimethylpyridine.The X-ray structures of 1a, 3, 4 and 5 have been determined.Compounds 2-4 are readily soluble in aromatic hydrocarbon solvents, while 5-8 are insoluble as a consequence of the presence of a supramolecular architecture involving dipolar In-Cl---N interactions in the solid state.All new compounds have been characterised by ¹H, ¹³C-<¹H> and ³¹P-<¹H> NMR and IR spectroscopy.

Full text of DOI:10.1039/DT9920002183

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:cis-dichloro-trans-(1,3-diphenyltriazenido)di(pyridine)indium(III)

Cas No:143672-22-4

R&D Labs maybe for 143672-22-4

Zibo Jujin Chemical Industry Co., Ltd.（Dongming Jujin Chemical Industry Co., Ltd. ）

Contact:+86-533-2975022

Address:No.99 Shanquan Road, Zhangdian District
Shanghai Yuking Water Soluble Material Tech Co., Ltd

Contact:86-21-68286299

Address:4F, 13B, No. 600, South Xinyuan Road 201306, Shanghai, China
Shanghai Bojing Chemical Co., Ltd.

Contact:021-37122233

Address:6F Buildiing 11,No.388,Baifu Road,District Fengxian.Shanghai, China.
Taizhou Shengxing Chempharm Co.,Ltd

Contact:+86-576-88516600

Address:Yantou Chemical Zone Jiaojiang Taizhou Zhejiang China
Xinji City Taida Sinopec Co., Ltd.

Contact:0086-311-85341278

Address:No.6, Nanhua Road,Xinji City Road,Hebei Province,China

Relevant to this article

REVISION OF THE ABSOLUTE CONFIGURATION OF A-FACTOR; THE INDUCER OF STREPTOMYCIN BIOSYNTHESIS, BASING ON THE RECONFIRMED (R)-CONFIGURATION OF (+)-PARACONIC ACID

Doi:10.1016/S0040-4020(01)91552-2
(1983)
Enantiomerically divergent pathways in Tsuji-Trost reactions: exploiting the structural differences between β-acyloxy-o-(diphenylphosphino)benzamides and β-amido-o-(diphenylphosphino)benzoates

Doi:10.1016/j.tetasy.2016.08.012
(2016)
A new CAN-catalyzed domino process related to the Nenitzescu reaction: Very concise access to fused ortho-indolequinones from simple precursors

Doi:10.1016/j.tet.2013.04.101
(2013)
Photo-induced electron transfer in a pyrenylcarbazole containing polymer-multiwalled carbon nanotube composite

Doi:10.1039/c3nj41086b
(2013)
Synthesis and Characterization of a Crown-Shaped 36-Molybdate Cluster and Application in Catalyzing Knoevenagel Condensation

Doi:10.1021/acs.inorgchem.0c01122
(2020)
The Phospha-Cope Rearrangement of 3-Phospha-1,5-hexadiene Derivatives Bearing a Hydroxyl Group

Doi:10.1246/cl.1992.1607
(1992)

Article Doi