Chemistry Letters p. 1607 - 1610 (1992)
Update date:2022-08-05
Topics:
Kawashima, Takayuki
Park, Dae Jong
Murata, Shinobu
Okazaki, Renji
Inamoto, Naoki
The title phospha-Cope rearrangement gives the corresponding cyclic phosphonates or phosphinates in 30 to 100percent yield.Stugies on solvent effects and kinetic isotope effects using the deuterated derivatives strongly support that there is a pre-equilibrium between tetracoordinate and pentacoordinate structures, followed by the rate-determinig phospha-Cope rearrangement.
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Doi:10.1016/S0040-4039(00)60115-6
(1992)Doi:10.1039/c39920001118
(1992)Doi:10.1021/jm301718c
(2013)Doi:10.1021/ol4010454
(2013)Doi:10.1007/BF00816852
(1992)Doi:10.1016/S0020-1693(00)92348-X
(1992)
