
Tetrahedron p. 3107 - 3109 (1983)
Update date:2022-08-05
Topics:
Mori, Kenji
(+)-Paraconic acid was shown to be of (R)-configuration by its four-step conversion to (R)-(+)-3-methyl-4-butanolide.The absolute configuration at C-3 of A-factor <2-(6-methylheptanoyl)-3-hydroxymethyl-4-butanolide> was therefore revised to be R, since it was synthesized from (S)-(-)-paraconic acid.
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(1992)