Solvatochromism in substituted 2,2'-bipyridinetetracarbonyl-metal complexes of chromium, molybdenum and tungsten

DOI: 10.1016/0022-328X(94)05058-J

Source and publish data:

Journal of Organometallic Chemistry p. 115 - 122 (1995)

Update date:2022-08-04

Topics:

Authors:

Baxter, Paul N. W.

Connor, Joseph A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(94)05058-J

The influence of various solvents on the electronic absorption spectra in the visible region of complexes of the general type (M = Cr, Mo, W; n = 3, 4, 5, 6; X = CH3, CN, CO2CH3; bipy = 2,2'-bipyridine) has been measured.Molar absorption coefficients are reported.Attempts to correlate this information with the solvent polarity parameter proposed by Manuta and Less indicate that the effects of geometric distortion in the substrate complex preclude a simple explanation of the observations in terms of a single parameter.Keywords: Chromium; Molybdenum; Tungsten; Solvatochromism; Bipyridine; Carbonyl

Full text of DOI:10.1016/0022-328X(94)05058-J

Products guided by the article

Product name:tetracarbonyl(3,3'-dimethyl-2,2'-bipyridine)molybdenum⁽⁰⁾

Cas No:143754-35-2

R&D Labs maybe for 143754-35-2

Taizhou Green Peptide Trading Co., Ltd.

Contact:--15314709780

Address:Room 1501, No71, Yuehe Road, Taizhou City, Zhejiang Province, China
Zhejiang Allied Chemical Co.,Ltd

Contact:18967038207

Address:Area A-30, High-tech Industrial Park, Quzhou, Zhejiang, China.
Zhengzhou Institute of Chiral Pharmer Research Co., Ltd.

Contact:86-371-55219111

Address:15 Floor, 2 Building, Central China Technovalley, Zhongyuan West Road
Jiande City Silibase Silicone New Material Manufacture Co., Ltd.

Contact:15967177856

Address:Genglou Industrial Development Area
Oren Hydrocarbons (Qingdao) Co., Ltd.

Contact:+86-532-68607667-801

Address:Room 3 # 302, No.9 Qingyun Road, Qingdao, China

Relevant to this article

Application of L-proline derivatives as chiral shift reagents for enantiomeric recognition of carboxylic acids

Doi:10.1002/chir.20948
(2011)
Stereochemistry and reactivity of pheylsulfonyl-substituted 2-azabicyclo[2.2.2]octan-6-ones

Doi:10.1002/ardp.19903231112
(1990)
Identification of 2-(4,5,6,7-tetrahydro-1H-pyrrolo[3,2-c]pyridin-3-yl)-ethylamine derivatives as novel GnRH receptor antagonists

Doi:10.1016/j.bmcl.2007.05.009
(2007)
Radical phosphination of organic halides and alkyl imidazole-1- carbothioates

Doi:10.1021/ja058783h
(2006)
Doi:10.1021/ja00735a035
(1971)
Synthesis of unsymmetrical benzils using N-heterocyclic carbene catalysis

Doi:10.1016/j.tet.2011.04.020
(2011)

Article Doi