Nucleophilic addition to coordinated polyenes: A novel method for the liberation of the trimethylenemethane ligand involving C-C bond formation

DOI: 10.1016/S0040-4039(00)74664-8

Source and publish data:

Tetrahedron Letters p. 4107 - 4110 (1992)

Update date:2022-07-30

Topics:

Authors:

Donaldson

Hossain Hossain

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Article abstract of DOI:10.1016/S0040-4039(00)74664-8

Reaction of (trimethylenemethane)Fe(CO)₃ with carbon nucleophiles, followed by protonation yields the corresponding methallylated nucleophile in good yield. Products which incorporate carbonyl ligands are also observed.

Full text of DOI:10.1016/S0040-4039(00)74664-8

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