Journal of the American Chemical Society p. 8424 - 8434 (1992)
Update date:2022-08-04
Topics:
Harvey, Daniel F.
Lund, Kevin P.
Neil, David A.
It has been observed that the reaction of 1,6- and 1,7-enynes with pentacarbonyl(butylmethoxycarbene)molybdenum(0) (18) produces vinylcyclopropanes in good to excellent yield.A systematic investigation into the factors which govern the success of these cyclizations has been performed.Chromium carbene complexes also lead to the formation of vinylcyclopropanes but in significantly lower yields.When the pathway to vinylcyclopropanes is not followed, a number of other distinct types of products are obtained.The pathways leading to these various products are discussed and compared.
View MoreQINGDAO TAOSIGN INTERNATIONAL TRADE CO.,LIMITED
Contact:+86-0532-82683616
Address:RM1402, Doublestar Seacoase 7#, No. 5 Guizhou Road, Qingdao, Shandong, China
Tianjin Emulsion Science&Technology Development Co.,Ltd
Contact:13901380442
Address:Vake Garden New Town New Yi Bai Road Beichen District Tianjin,China
Xuzhou Tianrun Chemical Co.,Ltd
website:http://www.tianrunchem.cn
Contact:86-516-83832636
Address:fuxing road
Contact:410-273-7300; 800-221-3953
Address:4609 Richlynn Dr., PO Box 369, Belcamp, MD, 21017-0369, USA
Chengdu Biopurify Phytochemicals Ltd.
website:http://www.phytopurify.com
Contact:+86-28-82633397
Address:2F,No.11 Building,No.388 Rongtaidadao CNSTP,Wenjiang Zone,Chengdu,Sichuan, China
Doi:10.1002/anie.201205728
(2013)Doi:10.1021/jf011140a
(2002)Doi:10.1021/ol401363t
(2013)Doi:10.1002/poc.3129
(2013)Doi:10.1016/S0040-4039(00)61291-1
(1992)Doi:10.1248/cpb.40.1647
(1992)