
Journal of the Chemical Society, Dalton Transactions p. 1957 - 1966 (1992)
Update date:2022-07-29
Topics:
Guilard, Roger
Jagerovic, Nadine
Tabard, Alain
Naillon, Christine
Kadish, Karl M.
The synthesis and characterization of nine indium(III) porphyrin complexes with three types of ?-bonded tetrazolato axial ligands are reported.The investigated compounds In(por)(N4CR) where R=CMe3, CH=CH2 or CH=CHCN and por = the dianion of 2,3,7,8,12,13,17,18-octaethylporphyrin (oep), 5,10,15,20-tetraphenylporphyrin (tpp) or 5,10,15,20-tetra-p-trifluoromethylphenylporphyrin (tfpp) were characterized by UV/VIS, IR and (1)H NMR spectroscopy as well as by electrochemistry.The N4CR ligand of a given M(por)(N4CR) complex can have the R group attached to either the 4 or 5 position of the tetrazolato ring and this is discussed in the present study with respect to the steric and electronic effects of the axial and equatorial ligands.
Beijing Cooperate Pharmaceutical Co.,Ltd
website:http://www.cooperate-pharm.com/
Contact:86-01060279497
Address:No.507,Building 4,Tianhua Street, Biomedicine industrial Base
Tianjin Jiuri New Materials Co., Ltd.
Contact:+86-22-58889220
Address:C-5/6, Vison Hill, No.1 Gonghua Road, Huayuan Hi-tech Park, Tianjin, China.
Zhengzhou Gecko Scientific Inc.
Contact:0371-88884176
Address:56 Hongzhuan Road, Zhengzhou, China
Taizhou Shengxing Chempharm Co.,Ltd
Contact:+86-576-88516600
Address:Yantou Chemical Zone Jiaojiang Taizhou Zhejiang China
Shenzhen Feiming Science and Technology Co,. Ltd
Contact:+86-755-85232577
Address:#B2309, Fenglin International Center ,Jixiang Road, Longcheng street, LongGang District, Shenzhen city, Guangdong province, China.
Doi:10.1039/c7ob01786c
(2017)Doi:10.1021/jo00178a018
(1984)Doi:10.1002/(SICI)1099-1344(200002)43:2<169::AID-JLCR302>3.0.CO;2-6
(2000)Doi:10.1007/s00726-019-02731-4
(2020)Doi:10.1002/adsc.201100778
(2012)Doi:10.1006/jcat.1995.1065
(1995)