Organic and Biomolecular Chemistry p. 3781 - 3785 (2013)
Update date:2022-09-26
Topics:
Patel, Alpesh Ramanlal
Ball, Graham
Hunter, Luke
Liu, Fei
Substituted azepanes are common bioactive epitopes with flexible ring structures. The conformational effects of monofluorination in model azepane rings were investigated by 1H NMR spectroscopy and computational modelling. A single fluorine atom, installed diastereoselectively, was found to bias the azepane ring to one major conformation for one diastereomer. The Royal Society of Chemistry 2013.
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