Synthesis of (E)-β,γ-unsaturated α-aminoacids by rearrangement of allyltrichloracetimidates

DOI: 10.1016/S0040-4039(00)74248-1

Source and publish data:

Tetrahedron Letters p. 4313 - 4316 (1992)

Update date:2022-08-03

Topics:

Authors:

Mehmandoust

Petit Petit

Larcheveque

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Article abstract of DOI:10.1016/S0040-4039(00)74248-1

Pure (E)-β,γ-unsaturated α-aminoacids of high enantiomerical purity were synthesized by Pd(II) catalyzed rearrangement of trichloracetimidates derived from optically pure monoprotected diallylalcohols. After cyclisation of the resulting N-trichloracetyl a

Full text of DOI:10.1016/S0040-4039(00)74248-1

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