A stereodivergent chirospecific synthesis of (3R) and (3S) 3-hydroxyaspartates by hydroxylation of aspartate diester enolates

DOI: 10.1016/S0040-4039(00)61333-3

Source and publish data:

Tetrahedron Letters p. 4637 - 4640 (1992)

Update date:2022-08-03

Topics:

Authors:

Sardina, F. Javier

Paz, Manuel M.

Fernandez-Megia, Eduardo

De Boer, Richard F.

Alvarez, M. Pilar

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Article abstract of DOI:10.1016/S0040-4039(00)61333-3

A chirospecific and stereodivergent synthesis of N-(9-phenylfluorenyl)-3-hydroxyaspartates by hydroxylation of aspartate enolates is described. The stereochemistry of the newly created chiral center is controlled by the nature of the enolate counterion an

Full text of DOI:10.1016/S0040-4039(00)61333-3

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Product name:(4R,5S)-4,5-Bis(methoxycarbonyl)-1-(9'-phenylfluoren-9'-yl)oxazolidin-2-one

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