A new synthesis of C-nucleosides by 1,3-dipolar cycloaddition of chiral azomethine imines to methyl acrylate. The stereoselective synthesis of fused pyrazoles

DOI: 10.1016/S0040-4020(01)80470-1

Source and publish data:

Tetrahedron p. 7965 - 7972 (1992)

Update date:2022-08-05

Topics:

Authors:

Zlicar Zlicar

Stanovnik

Tisler Tisler

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Article abstract of DOI:10.1016/S0040-4020(01)80470-1

A new stereoselective synthesis of C-nucleosides is described. The fused NH,NH-dihydro pyrazole derivative 1 was transformed with carbohydrates into chiral azomethine imines 2-4. The 1,3-dipolar cycloaddition of these to methyl acrylate affords the nucleo

Full text of DOI:10.1016/S0040-4020(01)80470-1

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