Synthesis of highly substituted symmetrical 1,3-dienes via organocuprate oxidation

DOI: 10.1055/s-0031-1290116

Source and publish data:

Synlett p. 298 - 300 (2012)

Update date:2022-07-29

Topics:

Authors:

Aves, Sarah. J.

O'Connell, Kieron M. G.

Pike, Kurt G.

Spring, David R.

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Article abstract of DOI:10.1055/s-0031-1290116

Oxidation of alkenyl organocuprates formed from alkenyl halides allows the formation of highly substituted symmetrical 1,3-dienes. Cuprates formed from organolithiums and Grignard reagents can be tolerated and the reaction proceeds with retention of alkenyl geometry. Georg Thieme Verlag Stuttgart New York.

Full text of DOI:10.1055/s-0031-1290116

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