A dual Lewis base activation strategy for enantioselective carbene-catalyzed annulations

DOI: 10.1021/ja405833m

Source and publish data:

Journal of the American Chemical Society p. 10634 - 10637 (2013)

Update date:2022-08-05

Topics: Yield Enantioselective Reaction Conditions Catalyst Loading Chiral Ligand Lewis base Carbene-catalyzed Annulations

Authors:

Izquierdo, Javier

Orue, Ane

Scheidt, Karl A.

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Article abstract of DOI:10.1021/ja405833m

A dual activation strategy integrating N-heterocyclic carbene (NHC) catalysis and a second Lewis base has been developed. NHC-bound homoenolate equivalents derived from α,β-unsaturated aldehydes combine with transient reactive o-quinone methides in an ena

Full text of DOI:10.1021/ja405833m

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