Stereocontrolled Synthesis of Calyculin A: Construction of the C(15)-C(25) Spiroketal Unit

DOI: 10.1039/c39920001236

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1236 - 1238 (1992)

Update date:2022-09-26

Topics:

Authors:

Barrett, Anthony G. M.

Edmunds, Jeremy J.

Horita, Kiyoshi

Parkinson, Christopher J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39920001236

Two concise enantioselective syntheses of the C(15)-C(25) spiroketal unit of calyculin A, using derivatives of allyldiisopinocampheylborane efficiently to control 1,2- and 1,3-diol stereochemistries, are reported.

Full text of DOI:10.1039/c39920001236

Products guided by the article

Product name:(2S,3S,5S,7R,8R,9S)-7-(2-Hydroxy-ethyl)-3-(4-methoxy-benzyloxy)-4,4,8-trimethyl-2-vinyl-1,6-dioxa-spiro[4.5]decan-9-ol

Cas No:144732-84-3

R&D Labs maybe for 144732-84-3

ShangHai BMG Chemical Co., Ltd

Contact:+86-13524845543

Address:Room 602, no 291 sikai road shanghai
Jiangsu Taihu New Materials Holding Co., Ltd

Contact:+86-519-86160108

Address:Xueyan Town, Changzhou City, Jiangsu Province, 213169, China
Pale Palm Imex

Contact:+36(21)2523420

Address:Head office: 1102 Budapest, SZENT LASZLO TER 24/B. 1/1., HUNGARY / CHINA
Hunan Dinuo Pharmaceutical Co.,Ltd.

Contact:86-731-88280100*8561

Address:Bio-pharmaceutical industrial park, Liuyang, Hunan, China
Shanghai Send Pharmaceutical Technology Co., Ltd.

website:http://www.shsendpharma.com

Contact:021-58088081, +8613585868794

Address::Room A601, Building 1,NO. 800 Qingdai Road Pudong District Shanghai,China

Relevant to this article

7-Hydroxy-(E)-3-phenylmethylene-chroman-4-one analogues as efflux pump inhibitors against Mycobacterium smegmatis mc² 155

Doi:10.1016/j.ejmech.2013.06.024
(2013)
Synthesis of diaryliodonium triflates using environmentally benign oxidizing agents

Doi:10.1055/s-0029-1217723
(2009)
Synthesis of 1,4-disubstituted 1,2,3-triazoles from aromatic α-bromoketones, sodium azide and terminal acetylenes via Cu/Cu(OTf) ₂-catalyzed click reaction under microwave irradiation

Doi:10.5560/ZNB.2013-3043
(2013)
Alkyl ferulates in wound healing potato tubers.

Doi:10.1016/0031-9422(92)83695-U
(1992)
Synthesis of 3-Sulfenylated Coumarins: BF₃·Et₂O-Mediated Electrophilic Cyclization of Aryl Alkynoates Using N-Sulfanylsuccinimides

Doi:10.1021/acs.joc.6b02271
(2016)
Synthesis of alaninyl and N-(2-aminoethyl)glycinyl amino acid derivatives containing the green fluorescent protein chromophore in their side chains for incorporation into peptides and peptide nucleic acids

Doi:10.1002/ejoc.200600729
(2007)

Article Doi