Stereocontrolled Synthesis of Calyculin A: Construction of the C(15)-C(25) Spiroketal Unit

DOI: 10.1039/c39920001236

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1236 - 1238 (1992)

Update date:2022-09-26

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Authors:

Barrett, Anthony G. M.

Edmunds, Jeremy J.

Horita, Kiyoshi

Parkinson, Christopher J.

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Article abstract of DOI:10.1039/c39920001236

Two concise enantioselective syntheses of the C(15)-C(25) spiroketal unit of calyculin A, using derivatives of allyldiisopinocampheylborane efficiently to control 1,2- and 1,3-diol stereochemistries, are reported.

Full text of DOI:10.1039/c39920001236

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