Asymmetric synthesis of aminopyrimidine and cyclic guanidine amino acids

DOI: 10.1016/j.tetlet.2013.06.066

Source and publish data:

Tetrahedron Letters p. 4526 - 4528 (2013)

Update date:2022-09-26

Topics:

Authors:

M?schwitzer, Vicki D.

Kariuki, Benson M.

Redman, James E.

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Article abstract of DOI:10.1016/j.tetlet.2013.06.066

Syntheses of amino acids with aminopyrimidine and cyclic guanidine side chains are described. The synthetic route employed Heck coupling of methyl 2-acetamidoacrylate to 4-methoxybenzyl protected 2-amino-5-iodopyrimidine, followed by Rh(I)-catalyzed asymm

Full text of DOI:10.1016/j.tetlet.2013.06.066

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