REACTIONS DE L'ortho-BIS(DIMETHYLSILYL)BENZENE AVEC LES NITRILES CATALYSEES PAR DES COMPLEXES DU RHODIUM

DOI: 10.1016/S0022-328X(00)84331-4

Source and publish data:

Journal of Organometallic Chemistry p. 301 - 308 (1982)

Update date:2022-09-26

Topics: Yield Selectivity Ligand Dehydrogenation Intermediate Oxidative Addition Reductive Elimination Solvent Effects Catalysis Hydrosilylation Substrate In Situ Monitoring Nitrites Rhodium Complexes Mechanistic study Silane NMR spectroscopy (Nuclear Magnetic Resonance) Turnover frequency (TOF) GC-MS (Gas Chromatography-Mass Spectrometry)

Authors:

Corriu, R. J. P.

Moreau, J. J. E.

Pataud-Sat, M.

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Article abstract of DOI:10.1016/S0022-328X(00)84331-4

The silylation reaction of nitriles using a bis-hydrosilane has been studied.The reaction of 1,2-bis(dimethylsilyl)benzene in the presence of as catalyst leads to a mixture of trans-N,N-disilated enamines and N,N-disilylated amines, the rati

Full text of DOI:10.1016/S0022-328X(00)84331-4

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