REACTIONS DE L'ortho-BIS(DIMETHYLSILYL)BENZENE AVEC LES NITRILES CATALYSEES PAR DES COMPLEXES DU RHODIUM

Article abstract of DOI:10.1016/S0022-328X(00)84331-4

The silylation reaction of nitriles using a bis-hydrosilane has been studied.The reaction of 1,2-bis(dimethylsilyl)benzene in the presence of as catalyst leads to a mixture of trans-N,N-disilated enamines and N,N-disilylated amines, the rati