The nonenzymatic cyclic dimerisation of 5-aminolevulinic acid

DOI: 10.1016/S0040-4020(01)80465-8

Source and publish data:

Tetrahedron p. 7879 - 7886 (1992)

Update date:2022-08-03

Topics:

Authors:

Butler Butler

George George

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Article abstract of DOI:10.1016/S0040-4020(01)80465-8

The nonenzymatic cyclic dimerisation of 5-aminolevulinic aid (5-ALA) leads to the formation of a pyrazine (3) and, under some circumstances, pseudo-porphobilinogen (1). On the other hand, the enzyme-catalysed process leads to porphobilinogen (PBG). The products of the former reaction were identified from their NMR spectra and mechanisms for their formation are proposed.

Full text of DOI:10.1016/S0040-4020(01)80465-8

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