Stereochemically Controlled Synthesis of Unsaturated Acids by the Coupled Baeyer-Villiger and Horner-Wittig Reactions: Synthesis of (Z)-Oct-6-enoic Acid

DOI: 10.1039/P19920002155

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 2155 - 2158 (1992)

Update date:2022-08-05

Topics:

Authors:

Levin, Daniel

Warren, Stuart

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/P19920002155

The lithium derivative of Ph2P(O)Et reacts with cyclohexene oxide to give largely one diastereoisomer of an alcohol.Oxidation to a ketone and then to a lactone followed by hydrolysis gives a Horner-Wittig intermediate and hence pure (Z)-oct-6-enoic acid.C

Full text of DOI:10.1039/P19920002155

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:-2-(1-Diphenylphosphinoylethyl)cyclopentanol

Cas No:144939-53-7

R&D Labs maybe for 144939-53-7

qingdao goldenchem imp and exp co.,ltd.

Contact:532-55579246

Address:no.62 ,haier road laoshan distirct
Ningbo Inno Pharmchem Co., Ltd.

Contact:86-574-87319282

Address:6F-5,NO.163 RUIQING RD.,NINGBO 315000 CHINA
Xiamen Goodhealth Pharmchem Co., Ltd.

Contact:0086-592-2097683

Address:404R No.2 54# Minzu Rd., Xiamen, China
Hangzhou Hysen Pharma co.,Ltd.

website:http://www.hysenpharma.cn/

Contact:0086-571-88298791

Address:#701,Gudun Road Hangzhou
Yangling Ciyuan biotech Co., Ltd.

Contact:86-15802970736

Address:2-1804, International Park Mansion, No.2, South Fengdeng Road, Lianhu District

Relevant to this article

Synthesis of new η⁶-(arene) chromium tricarbonyl complexes of isoxazolidines by 1,3-dipolar cycloaddition

Doi:10.1007/s11172-012-0290-4
()
Design and synthesis of novel FKBP inhibitors

Doi:10.1021/jm00101a005
(1992)
Chiral γ and δ Hydroxysulfones via Lipase Catalyzed Resolutions - Synthesis of (R)(+)-4-Hexanolide and (2R,5S)-2-Methyl-5-Hexanolide Using Intramolecular Acylation

Doi:10.1016/S0040-4020(01)81988-8
(1992)
Asymmetric synthesis of α,α-disubstituted amino acids by diastereoselective functionalization of enantiopure phenyloxazinones, derivatives of asymmetric Strecker reaction products of aldehydes

Doi:10.1016/S0040-4020(01)00502-6
(2001)
Novel peptidomimetic hepatitis C virus NS3/4A protease inhibitors spanning the P2-P1′ region

Doi:10.1021/ml400217r
(2014)
A divergent synthesis of 1,8-naphthyridines and hydropyridopyrimidinones by the reactions of o-aminonitriles with ketones

Doi:10.1002/cjoc.201201247
(2013)

Article Doi