Stereochemically Controlled Synthesis of Unsaturated Acids by the Coupled Baeyer-Villiger and Horner-Wittig Reactions: Synthesis of (Z)-Oct-6-enoic Acid

DOI: 10.1039/P19920002155

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 2155 - 2158 (1992)

Update date:2022-08-05

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Authors:

Levin, Daniel

Warren, Stuart

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Article abstract of DOI:10.1039/P19920002155

The lithium derivative of Ph2P(O)Et reacts with cyclohexene oxide to give largely one diastereoisomer of an alcohol.Oxidation to a ketone and then to a lactone followed by hydrolysis gives a Horner-Wittig intermediate and hence pure (Z)-oct-6-enoic acid.C

Full text of DOI:10.1039/P19920002155

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