Novel 1,5,3-dithiazepanes: Three-component synthesis, stereochemistry, and fungicidal activity

Article abstract of DOI:10.1007/s11172-012-0301-5

Three-component heterocyclization of hydrazine with formaldehyde and ethane-1,2-dithiol gave previously unknown 3,3′-bi(1,5,3-dithiazepane). Its stereochemistry was determined by X-ray diffraction. The reaction with higher aliphatic aldehydes RCHO (R = Me