An asymmetric synthesis of D-1,6-diepicastanospermine

DOI: 10.1016/S0040-4039(00)60010-2

Source and publish data:

Tetrahedron Letters p. 6077 - 6080 (1992)

Update date:2022-07-31

Topics:

Authors:

Burgess, Keyin

Chaplin, David A.

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Article abstract of DOI:10.1016/S0040-4039(00)60010-2

D-1,6-Diepicastanospermine has been prepared via reaction of an allylstannane with the arabinose derivative 1a. This reaction was almost 100 % stereoselective, but the corresponding allylations of aldehydes 1b-d gave mixtures of isomers. Variable stereodi

Full text of DOI:10.1016/S0040-4039(00)60010-2

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