Tetrahedron p. 7033 - 7048 (1992)
Update date:2022-08-02
Topics:
Wender, Paul A.
Rawlins, David B.
Model systems for the synthesis of the C and D rings of taxol are described, involving photolyses of α-methoxy ketones.Cis-fused oxetanols common to taxol are formed along with novel trans-fused oxetanols.Experiments bearing on the selectivity of this process as well as the mechanistic hypothesis are also described.
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