Convenient Syntheses of Optically Active Abscisic Acid and Xanthoxin

DOI: 10.1016/S0040-4020(01)80491-9

Source and publish data:

Tetrahedron p. 8229 - 8239 (1992)

Update date:2022-07-30

Topics:

Authors:

Sakai, Kunikazu

Takahashi, Kyoko

Nukano, Tomoko

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Article abstract of DOI:10.1016/S0040-4020(01)80491-9

The Reformatzky reaction of 3-(bromomethyl)crotonate with an optically active epoxycyclohexane aldehyde derivative (3), followed by dehydration, gave the chiral dienoic acid (6) stereospecifically.The product was derived to optically active abscisic acid (1) and xanthoxin (2) successfully.

Full text of DOI:10.1016/S0040-4020(01)80491-9

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