A NOVEL REARRANGEMENT OF TERTIARY α-ALLENIC ALCOHOL CARBAMATES. PREPARATION OF 2-O-CARBAMOYL-4,4-DISUBSTITUTED-1,3-BUTADIENES

DOI: 10.1016/S0040-4039(00)61758-6

Source and publish data:

Tetrahedron Letters p. 6715 - 6718 (1992)

Update date:2022-09-26

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Authors:

Friesen, Richard W.

Kolaczewska, Aleksandra E.

Khazanovich, Nina

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Article abstract of DOI:10.1016/S0040-4039(00)61758-6

Treatment of a variety of tertiary α-allenic alcohols with N-tosyl isocyanate results in a facile and novel rearrangement reaction that provides isolable 2-O-carbamoyl-4,4-disubstituted-1,3-butadienes in a stereoselective manner.

Full text of DOI:10.1016/S0040-4039(00)61758-6

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