Synthesis of optically active α-phenylselenyl carbonyl derivatives

DOI: 10.1016/S0957-4166(00)82087-X

Source and publish data:

Tetrahedron Asymmetry p. 1289 - 1302 (1992)

Update date:2022-09-26

Topics:

Authors:

Holmes Holmes

Nadin Nadin

O'Hanlon

Pearson Pearson

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Article abstract of DOI:10.1016/S0957-4166(00)82087-X

Homochiral silyl enol ethers derived from N-acyl oxazolidinones can be phenyselenylated in high diastereoselectivity and good yield with phenylselenyl chloride. Removal of the chiral auxiliary is accompanied by some epimerisation, leading to isolation of

Full text of DOI:10.1016/S0957-4166(00)82087-X

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Product name:3<4R,(Z)>-<1-<<(1,1-dimethylethyl)dimethylsilyl>oxy>-3-methyl-1-butenyl>-4-(1-methylphenyl)-2-oxazolidinone

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