Bull. Russ. Acad. Sci. Div. Chem. Sci. (Engl. Transl.) p. 1392 - 1394 (1992)
Update date:2022-08-05
Topics:
Petrushkina, E. A.
Zakharkin, L. I.
Isoprene and aniline have been reacted on the catalytic Pd(acac)2-Ph3P to form a mixture of isomeric telomers: N-(dimethyloctadien-2,7-yl-1)anilines and N-(dimethyloctadien-1,7-yl-3)anilines but on the catalytic system Pd(acac)2-Ph3P-CF3COOH the main product is a mixture of N-(methylbuten-2-yl)aniline adducts.The reaction between N-methylaniline and isoprene on the latter catalyst also gives a mixture of N-methyl and N-(methylbuten-2-yl)aniline adducts.Keywords: catalytic telomerization, terpenoid anilines.
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