Remarkable dependency of the regioselectivity in the ring opening of α,β-epoxyketones upon tin halide-Lewis base complexes as catalysts

DOI: 10.1016/S0040-4039(00)60859-6

Source and publish data:

Tetrahedron Letters p. 7149 - 7152 (1992)

Update date:2022-07-31

Topics:

Authors:

Shibata Shibata

Yoshimura

Baba Baba

Matsuda Matsuda

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Article abstract of DOI:10.1016/S0040-4039(00)60859-6

Tin halide-base complexes are used as catalysts for controlling the regioselectivity in the reaction of α,β-epoxyketones with electrophiles. Bu₂SnX₂-Ph₃P complex caused the cleavage of the C-O bond adjacent to the carbonyl

Full text of DOI:10.1016/S0040-4039(00)60859-6

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