Preparation, Spectroscopic and Structural Characterization of η1-N and η2-Se,Se' Complexes of a P2N4Se2 Ring

DOI: 10.1039/c39920001330

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1330 - 1332 (1992)

Update date:2022-08-03

Topics:

Authors:

Chivers, Tristram

Doxsee, Daniel D.

Hilts, Robert W.

Meetsuma, Auke

Parvez, Masood

Grampel, Johan C. van de

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39920001330

The reaction of 1,5-Ph4P2N4Se2, 1, prepared by the treatment of Ph2PN2(SiMe3)3 with a mixture of SeCl4 and Se2Cl2 in acetonitrile, with 2 gives the adducts _n<η¹-N-Ph4P2N4Se2> (2, n = 1; 3, n = 2) in which the P2N4Se2 ring is shown by an X-ray structural determination of 3 to contain a transannular Se-Se interaction; the oxidative addition of 1 or 2 to Pt(C2H4)(PPh3)2 produces the corresponding η²-Se,Se' complexes.

Full text of DOI:10.1039/c39920001330

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:PtCl₂(P(C₂H₅)3)Se(NP(C₆H₅)2N)Se(NP(C₆H₅)2N)Pt(P(C₆H₅)3)2

Cas No:146162-43-8

R&D Labs maybe for 146162-43-8

hangzhou sunchem trading co., ltd.

Contact:13588470430--

Address:Room 406-407, the 4th Building, No549
Shanghai Maxchemco Chemical Industry Co., Ltd.

Contact:(86)21-51079223

Address:No.1305-8, B241, the Ecust Park, Huajing Road, Xuhui District, Shanghai
Langchem

Contact:+86+21-58956006 15800617331

Address:402 Room, 150# Cailun Road, Zhangjiang high tech park, Shanghai
Shanghai Micro-mega Industry Co., Ltd.

Contact:0086-21-34628682;57153848

Address:Rm413,No.413,West Meilong Road, Minhang District,Shanghai P R China
Yixing Bluwat Chemicals Co., Ltd.

Contact:+86 510 87821568

Address:Yongan Road, Yixing Chemical Industrial Park, Yixing, Jiangsu, China

Relevant to this article

A convenient N-protection of pyroglutamate derivatives

Doi:10.1080/00397919508011481
(1995)
Complexes of the Platinum Metals. Part 41. Oxidative-substitution Reactions at Ruthenium(II) and Osmium(II) involving N,N'-Diphenylamidinate Ligands

Doi:10.1039/DT9920003199
(1992)
A convenient synthetic approach to new α-(9-fluorenylmethoxycarbonylamino)alkylphosphonic acid derivatives

Doi:10.1055/s-1992-26344
(1992)
Profiling human Src homology 2 (SH2) domain proteins and ligand discovery using a peptide-hybrid small molecule microarray

Doi:10.1039/c3cc45413d
(2013)
Stereoselective synthesis of enantiopure 4,5-disubstituted pyrrolidin-2-ones by consecutive cuprate addition and N-acyliminium coupling

Doi:10.1016/S0040-4039(00)74791-5
(1992)
Syntheses and NMR Behavior of Calix<4>quinone and Calix<4>hydroquinone

Doi:10.1021/jo00039a027
(1992)

Article Doi