Journal of the Chemical Society. Chemical communications p. 369 - 371 (1991)
Update date:2022-08-05
Topics:
Parsons, Simon
Passmore, Jack
Schriver, Melbourne J.
White, Peter S.
The rates of cycloaddition reactions of SNSAsF6 with alkynes and nitriles increase as the ionization potential (Ei) of the triple bond decreases, and accordingly reaction with HCCCN occurs preferentially at the CC bond; however, it reacts with NCCN quantitatively to give the dication
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