Mehrfachbindungen zwischen Hauptgruppenelementen und Uebergangsmetallen CXV. Dihalogenoxoosmium(VI)-Komplexe des Pinakols: Synthese, Spektroskopie und Alkylierung

DOI: 10.1016/0022-328X(92)85080-G

Source and publish data:

Journal of Organometallic Chemistry p. 363 - 368 (1992)

Update date:2022-07-31

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Authors:

Herrmann, Wolfgang A.

Watzlowik, Petra

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Article abstract of DOI:10.1016/0022-328X(92)85080-G

New dihalogen osmium(VI) complexes of pinacol (tetramethylglycol) are simply accessible by reaction of AlX3 (X=Cl, Br) with oxobis(pinacolato)osmium(VI).Alkylation by means of dialkylzinc reagents yields compounds containing two cis-oriented alkyl groups

Full text of DOI:10.1016/0022-328X(92)85080-G

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Product name:bis(pentafluorphenyl)(2,3-dimethylbutan-1,2-diolato)oxoosmium(VI)

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