Synthesis of atropisomeric biphenylbisphosphine, 6,6'-bis(dicyclohexylphosphino)-3,3'-dimethoxy-2,2',4,4'-tetramethyl-1, 1'-biphenyl and its use in rhodium(I)-catalyzed asymmetric hydrogenation

DOI: 10.1248/cpb.39.2767

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 2767 - 2769 (1991)

Update date:2022-07-31

Topics: Synthesis Ligand Enantiomeric excess (ee) Catalytic hydrogenation Chiral Resolution Asymmetric Hydrogenation Substrate Prochiral

Authors:

Murata Murata

Yamamoto

Yoshikawa

Morimoto

Achiwa Achiwa

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1248/cpb.39.2767

An optically pure atropisomeric biphenylbisphosphine, Cy-BIMOP, has been prepared, and its rhodium(I) complex showed higher catalytic activity and better enantioselectivity with the reverse configuration than BIMOP, p-MeO-BIMOP, and BINAP in the asymmetri

Full text of DOI:10.1248/cpb.39.2767

NII-Electronic Library Service

Products guided by the article

Product name:(RS)-6,6'-bis(dicyclohexylphosphoryl)-3,3'-dimethoxy-2,2',4,4'-tetramethyl-1,1'-biphenyl

Cas No:146611-81-6

R&D Labs maybe for 146611-81-6

Beijing Apis Biotechnology Co., Ltd.

Contact:86-010-67856775-8551

Address:NO.4PUHUANGYU ROAD,FENTAI DISTRICT, BEIJING, CHINA
Shanggao Ruiya Fine Chemicals Co., Ltd

Contact:+86-795-2592103

Address:Xingguang Nanlu,Shanggao County Industry Park
Liao Cheng All Win Chemicals Co.,LTD

Contact:86+0635-2991582

Address:Room 402,Unit 1,No.27 building.Zhong tong shi dai haoyuan,liaocheng city,Shan dong Province.China
Shanghai Zhihua ChemTech Co., Ltd.

Contact:+86-13774313779

Address:Room 817 Suite B 3333 Shenjiang Road
HuiFeiChem PharmaTech Co.Ltd

Contact:0510-85393305

Address:1619 Huishan Avenue, Huishan District, Wuxi,

Relevant to this article

1-Acetyl-4-methyl-3-cyclohexen-1-ol, a useful precursor in the synthesis of cyclic monoterpenes

Doi:10.1080/00397919208021634
(1992)
Scalable, Electrochemical Oxidation of Unactivated C-H Bonds

Doi:10.1021/jacs.7b03539
(2017)
Microwave Spectrum and Molecular Conformation of (E)-Benzaldehyde Oxime

Doi:10.1006/jmsp.1999.7882
(1999)
Unidirectional cis-trans photoisomerization of cis-3,3′-bis(diphenylhydroxymethyl)stilbene in inclusion complex crystals

Doi:10.1002/poc.693
(2003)
Gold(III)-catalyzed tandem reaction of O-arylhydroxylamines with 1,3-dicarbonyl compounds: Highly selective synthesis of 3-carbonylated benzofuran derivatives

Doi:10.1021/jo101357d
(2010)
Progestin 16α,17α-dioxolane ketals as molecular probes for the progesterone receptor: Synthesis, binding affinity, and photochemical evaluation

Doi:10.1021/jm00061a001
(1993)

Article Doi