Tetrahedron p. 6359 - 6366 (1993)
Update date:2022-08-06
Topics:
Sekigawa
Shimizu
Ando
Photoirradiation of polysilacycloalkynes in the presence of acetone provides the acetone adducts of bicyclic silacyclopropenes. Ring contraction of polysilacycloalkynes proceeds via two different pathways; one is a process via bicyclic silacyclopropene formed by rearrangement of the silicon atom adjacent to acetylene carbons and another is a direct desilylation process.
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