Allylation of Imidazoles. The Beneficial Effect of Imidazole Ligands on (?-Allyl)nickel Coupling

DOI: 10.1021/jo00057a006

Source and publish data:

Journal of Organic Chemistry p. 997 - 998 (1993)

Update date:2022-07-29

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Authors:

Knapp, Spencer

Albaneze, Jennifer

Schugar, Harvey J.

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Article abstract of DOI:10.1021/jo00057a006

The coupling of (?-allyl)nickel halide complexes with iodoimidazoles proceeds efficiently in toluene solution without the use of coordinating solvent or added ligand.Nickel-promoted allylation, and symmetrical coupling, of non-imidazole aryl halides is enhanced by using N-methylimidazole as an additive.

Full text of DOI:10.1021/jo00057a006

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