Journal of the American Chemical Society p. 2239 - 2248 (1993)
Update date:2022-08-03
Topics: Cyclopropane Deuterium Thermal stereomutations Sterechemistry
Baldwin, John E.
Selden, Christof B.
(-)-(1R,2R,3S)-1-Ethyl-2-methyl-1,2,3-trideuteriocyclopropane and (-)-(1S,2R,3R)-1-ethyl-2-methyl-1,2,3-trideuteriocyclopropane were synthesized and heated at 380°C in the gas phase; the thermal stereomutations shown by these substrates were followed as a
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