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Synthesis and Crystal Structures of a Series of Amide Copper(II) Complexes

DOI: 10.1039/DT9930000549

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 549 - 558 (1993)

Update date:2022-08-05

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Authors:

Alilou, El HoussineAlilou, El Houssine

Amadei, EdithAmadei, Edith

Giorgi, MichelGiorgi, Michel

Pierrot, MarcelPierrot, Marcel

Reglier, MariusReglier, Marius

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Article abstract of DOI:10.1039/DT9930000549

The synthesis and structural determination by X-ray crystallography of four amide copper(II) complexes has been performed: NH(CH2)nPh>(solv)>2 (X = H, solv = H2O, n = 2 1 or 1 2; X = OH, solv = H2O, n = 2 3; solv = MeCN, n = 1 4).In all complexes the co-ordination around the copper atom is a more or less distorted square-based pyramid where the three ligands of the square are unchanged: one oxygen atom of the amide group and two nitrogen atoms of the pyridine nucleus and of the tertiary amine.The fourth ligand is a water molecule (1-3) or an acetonitrile solvent molecule (4).The axial ligand is the oxygen atom of the phenolic group in complexes 3 and 4, while in 1 and 2 this site is occupied by an oxygen atom of a triflate counter ion.

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