TOTAL ASYMMETRIC SYNTHESES OF 3- AND 4-DEOXY-HEXOSES AND DERIVATIVES.

DOI: 10.1016/S0040-4020(01)88356-3

Source and publish data:

Tetrahedron p. 10587 - 10602 (1992)

Update date:2022-08-02

Topics:

Authors:

Fattori, Daniela

Vogel, Pierre

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Article abstract of DOI:10.1016/S0040-4020(01)88356-3

(1S,4S)-7-Oxabicyclo<2.2.1>hept-5-en-2-one ((-)-5, a "naked sugar") has been converted to (-)-(1R,4S,6S)-6-endo-benzyloxy-2-bromo-7-oxabicyclo<2.2.1>hept-2-ene ((-)-12) in a highly stereoselective fashion.Double hydroxylation of the C=C double bond of (-)

Full text of DOI:10.1016/S0040-4020(01)88356-3

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