Determination of the group electronegativity of CF3 group in 3'-O- CF3-thymidine by 1H-NMR

Article abstract of DOI:10.1080/15257779908041642

The interplay of enthalpy of the gauche effect (ΔH°(GE)) of the [X3'- C3'C4'-O4'] fragment in various 3'-substituted (X) 2',3'-dideoxythymidine derivatives 1 - 7 and the inherent anomeric effect drives the two-state North ? South equilibrium in the consti

Full text of DOI:10.1080/15257779908041642

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Determination of the Group
Electronegativity of CF3 Group in 3′-O-
CF3-Thymidine by 1-NMR
C. Thibaudeau a , N. Nishizono b , Y. Sumita b , A. Matsuda b & J.
Chattopadhyaya a
a Department of Bioorganic Chemistry, Biomedical Center ,
University of Uppsala , Box 581, S-751 23, Uppsala, Sweden
b Graduate School of Pharmaceutical Sciences, Hokkaido University ,
a Kita-12, Nishi-6, Kita-ku, Sapporo, 060-0812, Japan
Published online: 04 Oct 2006.
To cite this article: C. Thibaudeau , N. Nishizono , Y. Sumita , A. Matsuda & J. Chattopadhyaya
(1999) Determination of the Group Electronegativity of CF3 Group in 3′-O-CF3-Thymidine by 1-NMR,
Nucleosides and Nucleotides, 18:4-5, 1035-1053, DOI: 10.1080/15257779908041642
To link to this article: http://dx.doi.org/10.1080/15257779908041642
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