Syntheses and Properties of 5-Substituted (2,4)Pyridinophanes, Model Compounds of NAD(P)

Article abstract of DOI:10.1021/jo00060a018

(2,4)Pyridinophane derivatives 5-8 having an ester or an amide group at the 5-position were synthesized by aza-Wittig reactions between β-substituted vinyliminophosphoranes and cyclic α,β-unsaturated ketones. <β-(Methoxycarbonyl)vinyl>- (1), <β-(N,N-te