Tetrahedron Letters p. 8281 - 8284 (2001)
Update date:2022-08-05
Topics:
Dobler, Markus R
Bruce, Ian
Cederbaum, Fredrik
Cooke, Nigel G
Diorazio, Louis J
Hall, Roger G
Irving, Ed
The insecticidal activity found for rocaglamide and its congeners, prompted us to establish a short and efficient synthesis of the natural product and some synthetic 'halo-aryl' analogues. Pd-catalysed cross-coupling reactions of the bromo analogue were then explored in order to gain a suitable access to a broad range of unnatural analogues. The key step of our approach is a keto-aldehyde acyloin ring-closure followed by a Stiles carboxylation.
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Doi:10.1016/S0040-4039(00)77514-9
(1993)Doi:10.1021/jo00063a043
(1993)Doi:10.1246/bcsj.66.181
(1993)Doi:10.1007/BF02253029
(1997)Doi:10.1080/00397919308009806
(1993)Doi:10.1021/jo00061a045
(1993)