Journal of the Chemical Society, Dalton Transactions p. 1367 - 1372 (1996)
Update date:2022-07-29
Topics:
Araki, Koji
Lee, Sung-Kil
Otsuki, Joe
The copper(II) complex of 6,6′-bis(4-hexylbenzoylamino)-2,2′-bipyridine served as a new type of functional carrier in efficient and selective up-hill transport of anions across an organic liquid membrane. Reversible deprotonation of the amide groups of the ligand regulated the uptake and release of anions by alteration of the anion affinity of the complex, and affinity switching of the carrier by the pH of external aqueous solutions induced efficient up-hill transport of SCN- and toluene-p-sulfonate by coupling with a small pH difference across the membrane. The high thiocyanate selectivity of the carrier was ascribed to preferential axial coordination of SCN- to the complex which possesses an N2O2 square-planar structure.
View MoreZibo Fuxi'er Chemical Co.,Ltd （Shanxian Fuxi'er Chemical Co.,Ltd）
Contact:+86-533-2091422
Address:Eastern 4 on the 3th Road ,Liangxiang Industrial Park, Zibo city ,Shandong,China
SHANDONG CREDAGRI CHEMICAL CO., LTD.
Contact:+86-531-88872050
Address:ROOM 601A, BUILDING 2, SHUNTAI SQUARE, NO. 2000 SHUNHUA ROAD, HI-TECH DEVELOPMENT ZONE, JINAN, CHINA.
Hangzhou jls Flame Retardants Chemical Co.,Ltd
Contact:+86-571-87250387/87250386
Address:MOGANSHAN RODA 1418# SHANGCHENG INDUSTRIAL PARK
Weifang Yukai Chemical Co.,Ltd.
website:http://www.yukaichem.com/en.html
Contact:+86-536-8865336
Address:binhai economic development zone，262737 shangdong，china
Yueyang Hudex Pharmaceuticals Ltd.
Contact:0730-8748800
Address:Wujiang Bridge，Yueyang Economy & Technology Development Zone
Doi:10.1080/00397910802045592
(2008)Doi:10.1039/c8dt03137a
(2018)Doi:10.1039/c4cc03415e
(2014)Doi:10.1016/0223-5234(94)90111-2
(1994)Doi:10.1021/ic00115a009
()Doi:10.1021/ja00114a011
(1995)
