Highly regio-, (E)-stereo-, and diastereoselective SN2′ addition of organocuprates to chiral allylic cyclic carbonates

DOI: 10.1016/S0040-4039(00)60065-5

Source and publish data:

Tetrahedron Letters p. 91 - 94 (1993)

Update date:2022-08-04

Topics:

Authors:

Kang, Suk-Ku

Lee, Dong-Ha

Sim, Hyeong-Su

Lim, Jong-Suk

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Article abstract of DOI:10.1016/S0040-4039(00)60065-5

Reaction of the cyclic carbonates of acyclic vinyl diols with RCu(CN)Li· BF₃, RCu(CN)MgBr·BF₃, or RMgBr·CuI (cat) in THF at -78°C proceeded in S_N2′ fashion and resulted in the formation of alkylated (E)-allylic alcohols wi

Full text of DOI:10.1016/S0040-4039(00)60065-5

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