Novel Cyclization by Stannyl Anion Generated from Me3SiSnBu3 and F(1-). The Application to the Natural Product Synthesis

DOI: 10.1021/jo00063a012

Source and publish data:

Journal of Organic Chemistry p. 2972 - 2976 (1993)

Update date:2022-08-04

Topics:

Authors:

Mori, Miwako

Isono, Naohiro

Kaneta, Naotake

Shibasaki, Masakatsu

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Article abstract of DOI:10.1021/jo00063a012

Stannyl anion, generated from Me3SiSnBu3 and (Et2N)3S(1+)*TMSF2(1-) (TASF) or CsF in DMF, was quite effective for generation of an aryl or vinyl anion, which reacted with a carbonyl group intramolecularly to provide the useful cyclized product in good yield.

Full text of DOI:10.1021/jo00063a012

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Product name:2-Methyl-2-((E)-3-trimethylsilanyl-allyl)-cyclohexane-1,3-dione

Cas No:147974-04-7

R&D Labs maybe for 147974-04-7

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