Chemoenzymatic carbon-carbon bond formation leading to non-carbohydrate derivative. Stereoselective synthesis of pentamycin C-11-C-16 fragment

DOI: 10.1248/cpb.41.282

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Chemical and Pharmaceutical Bulletin p. 282 - 286 (1993)

Update date:2022-08-04

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Authors:

Shimagaki

Muneshima

Kubota Kubota

Oishi Oishi

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Article abstract of DOI:10.1248/cpb.41.282

Chemoenzymatic formation of 8 from an aldehyde 5 and dihydroxyacetone phosphate 6 was achieved by the use of fructose 1,6-diphosphate aldolase as a catalyst. Transformation of 8 to 20, corresponding to pentamycin C-11-C-16 fragment, was accomplished via 18a and 18b by chemical processes.

Full text of DOI:10.1248/cpb.41.282

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