Stereocontrolled syntheses of C-linked deoxyribosides of 2-hydroxypyridine and 2-hydroxyquinoline

Article abstract of DOI:10.1016/S0040-4039(00)92690-X

2′-Deoxy-C-ribosides 45 were prepared in optically active form by a route expected to be generally us for the synthesis of the α- or β-anomers of 2′-deoxy-C-ribosides. Key steps are the addition of an organometallic reagent to aldehyde 7, mesylation of th