STEREOCONTROLLED SYNTHESIS OF 6-epi-D-PURPUROSAMINE B BY IODOCYCLOCARBAMATION OF A CHIRAL Z-OLEFIN DERIVED FROM L-ALANINE AND L-MALIC ACID

Article abstract of DOI:10.1016/S0040-4039(00)96301-9

6-epi-D-Purpurosamine B was synthesized efficiently through a chiral Z-olefin 8 derived from L-alanine and L-malic acid under complete stereochemical control by using iodocyclocarbamation as the key reaction.