Journal of the Chemical Society, Faraday Transactions 2: Molecular and Chemical Physics p. 709 - 726 (1989)
Update date:2022-07-30
Topics:
Canosa-Mas, Carlos E.
Smith, Stuart J.
Toby, Sidney
Wayne, Richard P.
Arrhenius parameters have been measured over the temperature range 298-523 K for the hydrogen abstraction reactions of NO3 with CH3OH, CHCl3 and HCl. A rate constant was determined at room temperature for the reaction of NO3 with HBr. Kinetic data were obtained by the discharge-flow technique operating at total pressures between 1.8 and 5.2 mmHg. The rate expression derived for the interactions with CH3OH, CHCl3 and HCl are 1.2 x 10-12 exp (-2560/T), 8.6 x 10-13 exp (-2815/T), and 4.0 x 10-12 exp (-3330/T) cm3 molecule-1 s-1. For the reaction of NO3 with HBr, the rate constant is 1.3 x 10-16 cm3 molecule-1 s-1 at 298 K. The hydrogen-abstraction reactions of NO3 are compared with those of O(3P) and OH.
Hangzhou Bayee Chemical Co.,Ltd.
Contact:+86-571-86990109
Address:No.380, Jiangnan Auenue, Binjiang District, Hangzhou, China
Hefei Highzone Fine Chemical S&T CO.,LTD
Contact:86-0551-63663560
Address:room 1801 NO. 24 Shuguang RD.
chengdu firsterchem Pharmaceutical Co., Ltd.
Contact:028-66825849
Address:chengdu
Zhuhai Jiacheng Biological Technology Co., Ltd
Contact:0756-8800233
Address:room 222, Lianhua road , Gongbei ,Zhuhai, Guangdong ,China
CGeneTech (Suzhou, China) Co., Ltd.
Contact:+86-512-62956962
Address:Room 101，Bld C11,218 Xinghu Rd.,Suzhou industrial Park
Doi:10.1016/S0040-4020(01)90190-5
(1993)Doi:10.1016/0022-328X(93)80163-6
(1993)Doi:10.1139/v65-211
(1965)Doi:10.1016/j.ejmech.2013.09.024
(2013)Doi:10.1039/P29930000535
(1993)Doi:10.1016/S0040-6031(01)00834-6
(2002)
