TRANSITION METAL CARBONYLATES IN NUCLEOPHILIC AROMATIC SUBSTITUTION I. INFLUENCE OF IONIC ASSOCIATION ON THE RATES OF REACTIONS WITH PERFLUOROAROMATIC SUBSTRATES

Article abstract of DOI:10.1016/0022-328X(86)80233-9

Quantitative yields of monosubstituted products were obtained from the reactions between CpFe(CO)2^- (Cp=C5H5), Re(CO)5^- and C6F6, C5F5N; and CpW(CO)3^-, Mn(CO)5^- and C5F5N.The kinetics of the reactions of Re(CO)5