
Tetrahedron Letters p. 2203 - 2206 (1993)
Update date:2022-08-02
Topics:
Clayden, Jonathan
Collington, Eric W.
Brian Lamount
Warren, Stuart
Alkenyl oxazolidinones 5 have been made from the urethane derivatives 4 diphenylphosphinoyl epoxy alcohols 1 by a tandem intramolecular ring closure - Horner-Wittig elimination sequence. The stereoisomers of diphenylphosphinoyl epoxy alcohols containing further chiral centres have been made by enantio- and diastereoselective epoxidation, and converted stereo specifically to alkenyl oxazolidinones with 1,4-related chiral centres across a controlled geometry double bond.
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Doi:10.1016/S0040-4039(00)77625-8
(1993)Doi:10.1021/op980038k
(1998)Doi:10.1021/ja409344w
(2013)Doi:10.1016/S0040-4039(00)61581-2
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(1993)Doi:10.1016/S0040-4020(01)80381-1
(1993)