Mononuclear arylamido complexes of iridium(I)

DOI: 10.1021/om00031a001

Source and publish data:

Organometallics p. 2401 - 2403 (1993)

Update date:2022-09-26

Topics:

Authors:

Rahim, Marufur

White, Corbet

Rheingold, Arnold L.

Ahmed, Kazi J.

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Article abstract of DOI:10.1021/om00031a001

The preparation and the first structural characterization of arylamido complexes of Ir(I), having the general formula trans-Ir(CO)(NHAr)(PPh₃)₂, where Ar=Ph (1), p-C₆H₄Me (2), 2,6-C₆H₃Me₂ (3), are described. Preliminary results of their facile insertion reactions with CO and CO₂ are also discussed.

Full text of DOI:10.1021/om00031a001

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Product name:{Ir(CO)(NHC₆H₅)(P(C₆H₅)3)2}

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