Journal of Organic Chemistry p. 2678 - 2685 (1993)
Update date:2022-08-04
Topics:
Russell, Glen A.
Kulkarni, Shekhar V.
Acyl-substituted methyl radicals (RCOCH2.; R = H, Me, Ph), generated by photolysis of RCOCH2HgCl, add to alkenes, enol ethers, or vinyl sulfides to give adduct radicals that are readily trapped by PhSSPh to yield a three-component condensation product.The presence of an alkali metal carbonate is crucial in preventing side reactions resulting in the conversion of the mercurial to RCOCH3 by PhSH formed in the photolysis.
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Doi:10.1016/S0040-4039(00)60356-8
(1993)Doi:10.1039/c4ra14130j
(2015)Doi:10.1016/j.carres.2011.04.041
(2011)Doi:10.1021/om00031a030
(1993)Doi:10.1039/c39930000654
(1993)Doi:10.1016/S0957-4166(00)80160-3
(1993)
