Synthetic Studies on the Rhizoxins. 1. Two Stereoselective Routes to a Functionalized C1-C9 Subunit

DOI: 10.1021/jo00067a003

Source and publish data:

Journal of Organic Chemistry p. 3787 - 3788 (1993)

Update date:2022-08-03

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Authors:

Keck, Gary E.

Park, Min

Krishnamurthy, Dhileepkumar

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Article abstract of DOI:10.1021/jo00067a003

Two syntheses of a potential C1-C9 subunit of rhizoxin are described.In the first, chelation-controlled allylstannane addition to optically pure aldehyde 3, conversion to unsaturated ester 7, and stereoselective intramolecular Michael addition is used to

Full text of DOI:10.1021/jo00067a003

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